Time-Resolved X-Ray Absorption Spectroscopy Data for the Study of Chemical Reaction Intermediate States
نویسندگان
چکیده
Energy-dispersive X-ray absorption spectroscopy is an increasingly powerful tool for the investigation of kinetic processes in chemical systems as an element-specific local structure and electronic-state probe. In this paper we present a study of the structural evolution of the inner-sphere electron transfer reaction between [IrCl6] 2and [Co(CN)5] . The experimental requirements necessary for the extraction of maximal structural and electronic information are discussed.
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تاریخ انتشار 2006